涤纶长丝平滑剂的研制

论文编号:CL107  论文字数:8860,页数:19

摘要：有机硅由于其结构的独特性，所制成的平滑剂可赋予纺织物舒适，滑爽的手感。本实验以羟基封端的低分子量硅油（线性体）为主要原料，LiOH为催化剂，并选择带有不同官能团的偶联剂，在真空脱水状态下制备特种硅油。再经乳化获得涤纶长丝平滑剂。在此基础上，详细讨论了氨基改性硅油的制备、乳化及手感评价，并进行配方优化，结果表明：氨基含量15%、分子量5万左右的硅油，采用TX-3：TX-10=1：2的复合乳化剂乳化制得的氨基改性涤纶长丝平滑剂具有优异的性能。此外，我们还制备了环氧基、巯丙基、哌嗪基、脲基等改性的涤纶长丝平滑剂，通过性能评价发现，这些基团改性均不如氨基改性的涤纶长丝平滑剂的性能优异。

关键词：有机硅；平滑剂；涤纶长丝；乳化 
 
Abstract: Smoothing agent made of by Silicone ,which had a unique structure, can give textile fabrics comfort and smoothness handle. In this experiment, it used low molecular weight hydroxy-terminated silicone oil (linear) as the main raw material, LiOH as catalyst and selected coupling agent that with different functional groups, and prepared special silicone oil in a vacuum dehydration state. Then, Polyester Filament smoothing agent was gained by emulsion. On this  basis, it discussed the amino-modified silicone oil preparation, emulsifying , handle evaluation and formulation optimization in detailed. The results showed : the amino-modified polyester filament smoothing agent which was produced by amino-Content15%, molecular weight of about 50,000 silicone and composite emulsifying that used TX-3 : TX-10 = 1 : 2 had a excellent performance. Besides, we also prepared epoxy, mercapto-propyl, piperazine, urea-modified polyester filament smoothing agent, it found that the performance of amino-modified polyester filament smoothing is better than all of these.

Keywords：Silicone; Smoothing agent; Polyester filament; Emulsifying

目  录
中文摘要 I
英文摘要 II
目  录 III
1 绪论 1
1.1有机硅的结构与性能特点 1
1.1.1 结构特点 1
1.1.2 性能特点 1
1.1.3 有机硅适于纺织整理的结构优异性 2
1.2 各类改性的有机硅 2
1.2.1 线型非活性聚二甲基硅氧烷 2
1.2.2 反应性聚硅氧烷 3
1.2.3 氨基和酰胺基改性有机硅 3
1.3 有机硅硅油乳化 4
1.3.1　机械乳化法 4
1.3.2　乳液聚合法 5
1.3.3　转相乳液聚合法 5
1.4 本课题的提出 6
2 实验部分 6
2.1 实验主要原料和试剂 6
2.2 实验主要仪器和设备 7
2.3 实验步骤 7
2.3.1 硅油的制备 7
2.3.2 硅油的乳化 7
2.3.3 检测评定 7
3 结果与讨论 9
3.1 带氨基有机硅平滑剂合成 9
3.1.1 硅油合成工艺路线的讨论 9
3.1.2 氨基硅油的合成 9
3.1.3 氨基硅油乳化 9
3.1.4 性能评价结果 10
3.2 带其他官能团有机硅平滑剂合成 11
3.2.1 其他官能团硅油的合成 11
3.2.2 其他官能团硅油乳化 11
3.2.3 性能评价结果 12
4 结论与展望 13
致谢 14
参考文献 15