21st century is "green century" of sustainable development. As a new perspective, the green enterprises,from the view of enterprise and the environment, business and sustainable development, always stand the height of sustainable development. The green enterprises are rising the worldwide, but there is a big gap between our country and developed countries. Through the benefits analysis of Chinese green enterprises’ current situation and efficiency, we find the existing problems and put forward relevant measures to increase the effectiveness of green enterprises. Through promoting Chinese enterprises’ further transformation to the green business, we can rice the efficiency of resources reasonable allocation, use the limited natural resources and living environment reasonable to improve the welfare of consumers and human society and enhance the economic activities.